Flexible coordination polymers that can self-adjust, via closed (nonporous) to open (porous) switching, to match the size/shape of guest molecules are of particular interest. Herein, we reported C3 hydrocarbons can trigger a flexible SIFSIX network, [Cu(SiF 6 )(L) 2 ] n (L = 1,4-bis(1-imidazolyl)benzene), SIFSIX-23-Cu, to switch from nonporous to partially open phases at 298 K with different gate opening pressures (propyne < propylene < propane). The single-crystal x-ray diffraction (SCXRD) measurements have succeeded in crystallographic visualization of the C3-induced closed-to-open switching and the binding sites of gas molecules confined in the open phases. The results unambiguously showed the closed phase can undergo adaptive structural expansion upon sorption of different C3 molecules, and the conformation changes of L via rotation and contortion under gas loading are responsible for the structure transformation. The host-gas interactions are dominated by C-H•••F hydrogen bonds between gas molecules and SiF 6 2-anions and the size-matched chelation of linear propyne by SiF 6 2-pairs results in the stronger binding strength of propyne over propylene (propane), leading to the selective sorption of propyne from binary and ternary C3 gas mixtures, as confirmed by breakthrough experiments. This work highlights the vital role of host-gas interactions in governing the structural transitions and affords an efficient strategy to design high-performance flexible sorbents for challenging gas recognition and sorption.

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