Surface-localized phase mediation accelerates quasi-solid-state reaction kinetics in sulfur batteries

Grey, C. P. & Hall, D. S. Prospects for lithium-ion batteries and beyond—a 2030 vision. Nat. Commun. 11, 6279 (2020).

Article  CAS  PubMed  PubMed Central  Google Scholar 

Larcher, D. & Tarascon, J. M. Towards greener and more sustainable batteries for electrical energy storage. Nat. Chem. 7, 19–29 (2015).

Article  CAS  PubMed  Google Scholar 

Barrett, J. et al. Energy demand reduction options for meeting national zero-emission targets in the United Kingdom. Nat. Energy 7, 726–735 (2022).

Article  Google Scholar 

Wang, L. et al. Li-free cathode materials for high energy density lithium batteries. Joule 3, 2086–2102 (2019).

Article  CAS  Google Scholar 

Zhou, G., Chen, H. & Cui, Y. Formulating energy density for designing practical lithium–sulfur batteries. Nat. Energy 7, 312–319 (2022).

Article  CAS  Google Scholar 

Zhao, M., Li, B.-Q., Zhang, X.-Q., Huang, J.-Q. & Zhang, Q. A perspective toward practical lithium–sulfur batteries. ACS Cent. Sci. 6, 1095–1104 (2020).

Article  CAS  PubMed  PubMed Central  Google Scholar 

Su, C.-C., He, M., Amine, R., Chen, Z. & Amine, K. The relationship between the relative solvating power of electrolytes and shuttling effect of lithium polysulfides in lithium–sulfur batteries. Angew. Chem. Int. Ed. 57, 12033–12036 (2018).

Article  CAS  Google Scholar 

Li, Z., Zhou, Y., Wang, Y. & Lu, Y.-C. Solvent-mediated Li2S electrodeposition: a critical manipulator in lithium–sulfur batteries. Adv. Energy Mater. 9, 1802207 (2019).

Article  Google Scholar 

Hobold, G. M. et al. Moving beyond 99.9% Coulombic efficiency for lithium anodes in liquid electrolytes. Nat. Energy 6, 951–960 (2021).

Article  CAS  Google Scholar 

Liu, F. et al. Dynamic spatial progression of isolated lithium during battery operations. Nature 600, 659–663 (2021).

Article  CAS  PubMed  Google Scholar 

He, Q., Gorlin, Y., Patel, M. U. M., Gasteiger, H. A. & Lu, Y.-C. Unraveling the correlation between solvent properties and sulfur redox behavior in lithium–sulfur batteries. J. Electrochem. Soc. 165, A4027–A4033 (2018).

Article  CAS  Google Scholar 

Li, Z. et al. Correlating polysulfide solvation structure with electrode kinetics towards long-cycling lithium–sulfur batteries. Angew. Chem. Int. Ed. 62, e202309968 (2023).

Article  CAS  Google Scholar 

Manthiram, A. A reflection on lithium-ion battery cathode chemistry. Nat. Commun. 11, 1550 (2020).

Article  CAS  PubMed  PubMed Central  Google Scholar 

Fan, F. Y. & Chiang, Y.-M. Electrodeposition kinetics in Li–S batteries: effects of low electrolyte/sulfur ratios and deposition surface composition. J. Electrochem. Soc. 164, A917–A922 (2017).

Article  CAS  Google Scholar 

Lim, W.-G., Kim, S., Jo, C. & Lee, J. A comprehensive review of materials with catalytic effects in Li–S batteries: enhanced redox kinetics. Angew. Chem. Int. Ed. 58, 18746–18757 (2019).

Article  CAS  Google Scholar 

Kwon, H., Baek, J. & Kim, H.-T. Building lithium metal batteries under lean electrolyte conditions: challenges and progress. Energy Storage Mater. 55, 708–726 (2023).

Article  Google Scholar 

Park, J.-W. et al. Solvent effect of room temperature ionic liquids on electrochemical reactions in lithium–sulfur batteries. J. Phys. Chem. C 117, 4431–4440 (2013).

Article  CAS  Google Scholar 

Suo, L., Hu, Y.-S., Li, H., Armand, M. & Chen, L. A new class of solvent-in-salt electrolyte for high-energy rechargeable metallic lithium batteries. Nat. Commun. 4, 1481 (2013).

Article  PubMed  Google Scholar 

Zheng, J. et al. High-fluorinated electrolytes for Li–S batteries. Adv. Energy Mater. 9, 1803774 (2019).

Article  Google Scholar 

Yamada, Y., Wang, J., Ko, S., Watanabe, E. & Yamada, A. Advances and issues in developing salt-concentrated battery electrolytes. Nat. Energy 4, 269–280 (2019).

Article  CAS  Google Scholar 

Cao, X. et al. Monolithic solid–electrolyte interphases formed in fluorinated orthoformate-based electrolytes minimize Li depletion and pulverization. Nat. Energy 4, 796–805 (2019).

Article  CAS  Google Scholar 

Pang, Q. et al. Tuning the electrolyte network structure to invoke quasi-solid state sulfur conversion and suppress lithium dendrite formation in Li–S batteries. Nat. Energy 3, 783–791 (2018).

Article  CAS  Google Scholar 

Liu, Y. et al. Stabilized Li–S batteries with anti-solvent-tamed quasi-solid-state reaction. Joule 7, 2074–2091 (2023).

Article  CAS  Google Scholar 

Lee, C.-W. et al. Directing the lithium–sulfur reaction pathway via sparingly solvating electrolytes for high energy density batteries. ACS Cent. Sci. 3, 605–613 (2017).

Article  CAS  PubMed  PubMed Central  Google Scholar 

Shin, M. et al. Effect of the hydrofluoroether cosolvent structure in acetonitrile-based solvate electrolytes on the Li+ solvation structure and Li–S battery performance. ACS Appl. Mater. Interfaces 9, 39357–39370 (2017).

Article  CAS  PubMed  Google Scholar 

Askins, E. J. et al. Triarylmethyl cation redox mediators enhance Li–O2 battery discharge capacities. Nat. Chem. 15, 1247–1254 (2023).

Article  CAS  PubMed  Google Scholar 

Ahn, S. et al. Why charging Li–air batteries with current low-voltage mediators is slow and singlet oxygen does not explain degradation. Nat. Chem. 15, 1022–1029 (2023).

Article  CAS  PubMed  Google Scholar 

Lei, J. et al. An active and durable molecular catalyst for aqueous polysulfide-based redox flow batteries. Nat. Energy 8, 1355–1364 (2023).

Article  CAS  Google Scholar 

Meini, S., Elazari, R., Rosenman, A., Garsuch, A. & Aurbach, D. The use of redox mediators for enhancing utilization of Li2S cathodes for advanced Li–S battery systems. J. Phys. Chem. Lett. 5, 915–918 (2014).

Article  CAS  PubMed  Google Scholar 

Gerber, L. C. H. et al. Three-dimensional growth of Li2S in lithium–sulfur batteries promoted by a redox mediator. Nano Lett. 16, 549–554 (2016).

Article  CAS  PubMed  Google Scholar 

Tsao, Y. et al. Designing a quinone-based redox mediator to facilitate Li2S oxidation in Li–S batteries. Joule 3, 872–884 (2019).

Article  CAS  Google Scholar 

Liu, Y. et al. Electrolyte solutions design for lithium–sulfur batteries. Joule 5, 2323–2364 (2021).

Article  CAS  Google Scholar 

Amine, R. et al. Regulating the hidden solvation-ion-exchange in concentrated electrolytes for stable and safe lithium metal batteries. Adv. Energy Mater. 10, 2000901 (2020).

Article  CAS  Google Scholar 

Ding, W., Lei, X. & Ouyang, C. Coordination of lithium ion with ethylene carbonate electrolyte solvent: a computational study. Int. J. Quantum Chem. 116, 97–102 (2016).

Article  CAS  Google Scholar 

Shen, Z. et al. Cation-doped ZnS catalysts for polysulfide conversion in lithium–sulfur batteries. Nat. Catal. 5, 555–563 (2022).

Article  CAS  Google Scholar 

Li, Z. et al. Lithiated metallic molybdenum disulfide nanosheets for high-performance lithium–sulfur batteries. Nat. Energy 8, 84–93 (2023).

Article  CAS 

Comments (0)

No login
gif